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In 1881, Arthur R, Hantzsch first reported the dihydropyridine molecule through a one-pot reaction of two moles of ethyl acetoacetate with carbonyl compound and nitrogen source (ammonia or ammonium acetate) (Scheme 1) ( I ) and chalcone ( II ) intermediates and further underwent cyclisation to generate a 1,4-dihydropyridine product (Scheme 2) (Figure 1)

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Their active redox centers have heme, cysteine thiols, selenium, manganese, and other chemical moieties