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Finally, conversion of natural product 9 into ent −1 β -hydroxy-16-ketobeyeran-19-oic acid ( 2 ) 43 could be effected through a selective Dess-Martin oxidation of the more accessible C16 hydroxyl group, which may also be consistent with a relief of torsional strain upon rehybridization at C16 from sp 3 to sp 2 (Fig

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The pain associated with melittin is due to the depolarization of nerve endings by these tetramers